Atomic Resolution Images In Air Of Highly Ordered Pyrolytic Graphite (HOPG) Using STM Equipment From NanoSurf

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Background

Graphite Structure

Background

In a good top view image of Highly Ordered Pyrolytic Graphite (HOPG) you will see a pattern consisting of white, grey and black spots. To interpret the image correctly: the bright spots mean higher tunneling current and dark spots mean low current.

AZoNano - The A to Z of Nanotechnology Online - STM image of Highly Ordered Pyrolytic Graphite

Figure 1. STM image of Highly Ordered Pyrolytic Graphite, 2x2nm image

Graphite Structure

Out of the lattice model of graphite one can see that there are two different positions of the carbon atoms in the graphite crystal lattice (see e.g. R.C. Tatar et al. Phys Rev B 25 (1982) 4126).

AZoNano - The A to Z of Nanotechnology Online - Illustration of the carbon atom position

Figure 2. Illustration of the carbon atom position

One with a neighbouring atom in the plane below (grey) and one without a neighbour in the lattice below (white). Consequently the electrical conductivity of the graphite surface varies locally slightly (different electronic density of states) so that the atoms without neighbours appear "higher" than the others (see e.g. I.P. Batra et al. Surf Sci 181 (1987) 126). This also causes the lattice constant between the bright 'hills' to have the higher value of 0.25nm than the nearest neighbour distance in the graphite lattice of 0.14nm.

AZoNano - The A to Z of Nanotechnology Online - Out of the lattice model of graphite

Figure 3. Out of the lattice model of graphite

Source: Nanosurf

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Date Added: Feb 23, 2007 | Updated: Jun 11, 2013
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