Topics CoveredNew Transmission Plates Improving Thickness
Uniformity of ICP-CVD Deposited FilmsAchieving Better Film
Performance with ICP-CVD Systems from Oxford Instruments Controlling Gas Flows During ICP-CVD ProcessingRepeatability and Stability of ICP-CVD ProcessingDeposition of Materials Using ICP-CVD ProcessingChamber Plasma Cleaning and ICP-CVD
Processing Chamber Plasma
Cleaning and Typical Thickness Guidelines Plasma
New Transmission Plates Improving Thickness Uniformity of
ICP-CVD Deposited Films
Process improvements have also been made in which improved film thickness
uniformity has been achieved based on our new patented hardware design. The new
hardware design also allows the user the ability to deposit layers over larger
areas with excellent film thickness uniformity. The patented hardware design is
based on a new style showerhead design which we call a transmission plate. The
transmission plate is then placed in the chamber and sits between the high
density plasma source and the substrate.
The transmission plate has been optimized by adjusting the hole sizes and
distribution in order to achieve maximum film thickness improvement. The
transmission plate is made of the aluminium alloy 6082 with sufficient thickness
to maintain the plate close to the chamber temperature by lateral conduction,
even when running with high ICP powers. It was found that in order to achieve
“best” film thickness uniformity for silicon nitride and silicon oxide
depositions two different variants of the plates were required.
Figures 1 and 2 (below) show two different transmission plates for an ICP180
Figure 1. Image of the silane gas ring and gas
transmission plate inside the process chamber during a plasma process
Figure 2. Two gas transmission plates. (a) Transmission
plate 1 is optimised to deposit SiO2. (b) Transmission plate 2 is
optimised to deposit SiNx
Figure 3 shows a larger transmission plate which is required for the ICP380
source in order to deposit ICP- CVD films with substrates up to 300mm with excellent film
Figure 3. Transmission plate used with the ICP380
Improving Film Performance with ICP-CVD Systems from Oxford
Figure 4 and 5 shows an example of SiNx film thickness
distribution over 100 mm and 200mm silicon wafer, using an ICP180 and
an ICP380 source respectively. Oxford
Instruments’ ICP-CVD systems now offer these improved process improvements,
and users will also be able to easily upgrade their existing ICP-CVD
system in order to able to achieve even better film performance.
Figure 4. ICP-CVD SiNx film thickness
uniformity over 100mm using a System100 with an ICP180 source
Figure 5. ICP-CVD SiNx film thickness
uniformity over 200mm using a System100 with an ICP380 source
Typical film thickness uniformity performance for low temperature depositions
also depends on the ICP source used. Table 1 shows the different film thickness
uniformity depending on the ICP source.
Table 1. Typical ICP-CVD film thickness
Controlling Gas Flows During ICP-CVD Processing
Deposited films such as Silicon nitride and silicon oxide are used in HBLEDS
to passivate the final devices. Current methods include batch PECVD processing
which has a typical load of up to 8 x 4” substrates (and a much larger load of
2” substrates) with a growth rate of 14-15 nm/min. Considerable amount of
interest recently have been directed towards single wafer LED processing which
requires higher deposition rates to maintain throughput requirements. It is also
known that the deposition temperature must also be kept as low as possible.
These requirements restricts the ability of conventional PECVD which require
high temperatures and low deposition rates in order to allow high quality
material to be deposited, probably through allowing sufficient time for excess
hydrogen to outgas from the growing film.
We have already discussed that high density films can be deposited at low
temperatures (<150°C) using the ICP-CVD
technique but with typical deposition rates of 8nm/min. However recent
development work at OIPT has achieved much higher deposition rates of >
140nm/min at the same low temperatures, whilst maintaining good film quality,
film thickness uniformity and film stress control. These recent advances have
shown the capability of ICP-CVD in achieving high quality films at low temperatures
with high throughput. The higher deposition rate processes were achieved by
increasing the ICP power and gas flow mixture as shown in figure 6 below. The
gas flow ratio for SiN and SiO2 deposition were then adjusted in
order to tune the refractive index (figure 7).
Figure 6. Variation of deposition rate with total gas
flows for ICP-CVD SiNx deposited at 150°C
Figure 7. Variation of deposition rate versus total gas
flows for ICP-CVD SiO2 deposited at 150°C
Repeatability and Stability of ICP-CVD Processing
One of the most important factors of a deposition system is the ability to
deposit the same film over and over again. The repeatability and stability of
the ICP-CVD process in which tests have been carried out by
depositing high deposition rate SiO2 (>140nm/min) at low
temperatures (<150°C) on 75 x 100mm wafers. Results are shown in figure 8, 9,
and 10 below.
Figure 8. Wafer to wafer deposition rate repeatability of
<+/-2% with film thickness uniformity of <+/-3% over 100mm wafer
Figure 9. Wafer to wafer refractive index repeatability
Figure 10: ICPCVD SiO2 film stress
repeatability over 75 wafers
Figure 11: Effect of phosphorous gas flow on ICP-CVD a-Si
Deposition of Materials Using ICP-CVD Processing
In addition to SiO2, SiOxNy and
SiNx layers ICP-CVD can also be used to deposit other materials such as
amorphous silicon (undoped and doped) and silicon carbide.
Amorphous silicon is usually deposited using pure silane with small flows of
argon in order to help strike the plasma. Additional hydrogen is also used in
order to improve the film quality. Dopants can be added in the form of
phosphorus and boron in order to change the conductivity of the layer which is
particular important in photovoltaics applications. Figure 11 below the effect
of Phosphorous flow on deposition rate for ICP-CVD
amorphous si layers.
ICP-CVD can also be used to deposit silicon carbide. Silane is
normally mixed with methane and argon is also used to help with plasma striking.
The refractive index of the SiC can be tuned by adjusting the gas flow ratio of
silane to methane. Figure 12 and 13 shows the relationship between refractive
index, film stress and methane/silane gas flow ratio.
Figure 12: Variation of refractive index with
methane/silane gas flow ratio
Figure 13: Variation of film stress with methane / silane
gas flow ratio
Chamber Plasma Cleaning and ICP-CVD Processing
In ICP-CVD processing, a significant proportion of the tool time
is devoted to plasma cleaning using etching gases to clean the process chamber.
There are a number of clean gases available such CF4,
C3F8, C2F6 and NF3.
However in our ICP chambers we nominally use SF6 due to ability to
achieve higher etching rates, cleaner by products and experienced etching
processes which we have modified in order to successfully clean inside the
chamber. Alternative gases which we have also used are CF4 and
The clean gases whether its SF6 or CF4 is usually used
with either O2 or N2O in order to reduce the by products
formed after the clean. The clean consists of using the ICP power and also power
to the electrode. This is used to promote the fluorine in order to achieve
faster etching rates. A wafer is also suggested to be placed on the table in
order to protect the surface i.e. reduce over cleaning in this area. The plasma
cleaning time and the cleaning intervals depends on the nature of the
deposition. For example if a high stress film is deposited in the chamber then
the maximum deposition before cleaning is required is reduced due to the
potential of the film flaking from the chamber walls onto the sample.
Chamber Plasma Cleaning and Typical Thickness Guidelines
Typical thickness and cleaning guidelines are shown below.
- Cleaning should be carried out after >5microns of film deposition.
- Cleaning time is dependent on type and thickness of film deposited.
- Typical cleaning time is 2hours for 6-8 microns of film deposition.
Following a plasma chamber clean it is important to run a pump purge recipe
in order to minimise particulates. A typical sequence is shown below:-
Repeat 30 times/1min pump/1min N2 purge, 100sccm, 50mT/Loop
Conditioning of the chamber is an important step in order to achieve a
repeatable process. We have observed that ~0.5microns of deposition is required
for conditioning. Figure 14 shows how the deposition rate and refractive of the
process stabilises after a chamber plasma clean and chamber conditioning.
Figure 14: Effect of chamber conditioning on process
Plasma Pre-Treatment Processes
A plasma pre-treatment process can be applied to a particular surface in
order to avoid delamination of the deposited films especially when the film
comes under some thermal or mechanical stress. Good adhesion of the deposited
films onto the underlying material depends on the type of surface and also the
type of residues on the surface. Oxygen based plasma pre-clean has the greater
effect in removing organic residues whereas a hydrogen based plasma preclean has
the greater effect removing inorganic residues.
If a substrate material other than Silicon is used such as Gallium Arsenide
or Gallium nitride a plasma pre treatment process is essential to achieve good
film properties. For example, adhesion and quality of the deposited film can be
improved by applying a hydrogen based pre clean process prior film deposition.
This has been carried out by using an ammonia/nitrogen plasma pre clean where
the ammonia dissociates into nitrogen and hydrogen and the resulting hydrogen
attacks the underlying surface giving a hydrogenated surface which provides a
good interlayer between film and substrate. The subsequent deposited film then
shows good film properties such as good adhesion, low pinholes and good
In this paper we have shown that ICP-CVD can
be used to deposit various materials including SiO2, SiNx,
a-Si and SiC. By using the ICP-CVD technique high quality films are deposited with high
density plasma, low deposition pressures and temperatures which results in
minimizing film contamination, promoting film stoichiometry, reducing radiation
damage by direct ion-surface interaction, and eliminating device degradation at
Source: "Inductively coupled plasma chemical vapour deposition
(ICP-CVD)" by Oxford Instruments Plasma Technology.
For more information on this source please visit Oxford Instruments