Tiny objects known as nanoparticles are often heralded as holding great potential
for future applications in electronics, medicine and other areas. The properties
of nanoparticles depend on their size and structure. Now researchers from North
Carolina State University have learned how to consistently create hollow,
solid and amorphous nanoparticles of nickel phosphide, which has potential uses
in the development of solar cells and as catalysts for removing sulfur from
fuel. Their work can now serve as a "how-to" guide for other researchers
to controllably create hollow, solid and amorphous nanoparticles - in order
to determine what special properties they may have.
The study provides a step-by-step analysis of how to create solid or hollow
nanoparticles that are all made of the same material. "It's been known
that these structures could be made," says Dr. Joe Tracy, an assistant
professor of material science engineering at NC State and co-author of the paper,
"but this research provides us with a comprehensive understanding of nanostructural
control during nanoparticle formation, showing how to consistently obtain different
structures in the lab." The study also shows how to create solid nanoparticles
that are amorphous, meaning they do not have a crystalline structure.
Tracy explains that there is a great deal of interest in the formation of hollow
nanoparticles and amorphous nanoparticles. But for many kinds of nanoparticles,
there had previously been no clear understanding of how to control the formation
of these structures. As a result of the new study, Tracy says, "nanoparticles
with desired structures can be made more consistently, making it easier for
researchers to determine their electronic, optical and catalytic properties."
For example, amorphous nanoparticles may be of use in future electronic applications
or for nanostructure fabrication. Tracy stresses that while the NC State researchers
were able to show how to create hollow nanoparticles and amorphous nanoparticles,
they were not able to create nanoparticles that were both hollow and amorphous.
The study could also have implications for many additional types of nanoparticles,
not just nickel phosphide. Tracy says that the findings "could provide
important insights for further studies to control the structures of many other
kinds of nanoparticles, with a wide array of potential applications." These
could include metal oxide, sulfide, selenide and phosphide nanoparticles.
Specifically, the researchers found that they could control whether nickel
phosphide nanoparticles would be hollow or solid by adjusting the ratio of phosphorus
to nickel reactants when they synthesized the nanoparticles. The researchers
found that they could create amorphous solid nanoparticles by controlling the
temperature.
The study, "Nickel Phosphide Nanoparticles with Hollow, Solid, and Amorphous
Structures," was co-authored by Tracy, NC State post-doctoral researcher
Junwei Wang and NC State Ph.D. student Aaron Johnston-Peck. The research was
funded by NC State and the National Science Foundation, and was published online
by Chemistry of Materials.
Posted September 24th, 2009
