Posted in | News | Graphene

Sustainable Synthesis of Carbon-Based Oxygen Reduction Reaction Electrocatalyst

Graphitic carbon nitride/graphene hybrids for electrocatalysis of oxygen reduction reactions (ORR) in metal-air fuel cells and batteries are proven to be viable, inexpensive, and long-lasting alternatives for platinum-based electrocatalytic materials.

Sustainable Synthesis of Carbon-Based Oxygen Reduction Reaction Electrocatalyst​​​​​​​

​​​​​​​Study: Graphitic carbon nitride on reduced graphene oxide prepared via semi-closed pyrolysis as electrocatalyst for oxygen reduction reaction. Image Credit: pinkeyes/Shutterstock.com

In a study published in the journal Materials Chemistry and Physics, a simple approach for producing graphitic carbon nitride on reduced graphene oxide was shown using semi-closed pyrolysis of graphene oxide and urea in ambient conditions contributing to viable carbon-based ORR electrocatalysts.

An Introduction to Oxygen Reduction Reactions

The oxygen reduction reaction is critical in energy studies since it accounts for about 50% of the total electrolytic processes in air-breathing fuel cells and batteries.

Owing to the many adsorptive or desorption steps that happen throughout the process, which generally lead to the formation of diverse oxygen species (like O, O2-, H2O, OH-, H2O2), the ORR is renowned for being slow and permanent in an aqueous setting.

As it is well understood that the oxygen reduction reaction is the kinetically restricting element in most electrolytic energy systems, attempts are being made to optimize the reaction using electrocatalysis.

Carbon-based Nanotechnology – The Future of Fuel Cells?

Carbonaceous nanostructures have fueled interest following a growing desire for cost-effective resistance against corrosion, high contact areas, varied pore architectures, surface and bulk properties, and environmental compatibility.

Nitrogen-containing carbonaceous nanostructures had been demonstrated to be a viable, inexpensive, and poisoning-resistant alternative for ORR electrocatalysts based on platinum, with some having similar or better ORR action than the more costly alternatives like platinum-based electrocatalysts.

As a result of their graphitic and nitrogen-rich nanoscale architecture, graphitic carbon nitrides (g-C3N4) have the highest promise for ORR electrocatalysis. g-C3N4, often used for photocatalysis in organic contaminant decomposition,  was previously underutilized as a possible ORR electrocatalyst because of its low conductance.

Using an additional carbonaceous supporting framework, like graphene, enhances the conductance and surface area of g-C3N4, resulting in improved usability for ORR electrocatalysis.

Semi-Closed Pyrolysis Vs. Existing Synthesis Techniques

A review of the existing research found that most approaches for producing g-C3N4@graphene composites depend on tubular furnaces filled with nitrogen or argon gas, which offers an oxygen-free environment for the pyrolytic process but restricts the process's scaling potential.

Furthermore, most synthesis methods begin with g-C3N4 precursors which are potentially harmful to people or the planet or extremely volatile and challenging to manufacture on a bigger scale.

Functionally speaking, semi-closed pyrolysis may be defined as the high heat, thermochemical transformation of materials in ambient pressure and atmospheric settings. Semi-closed pyrolysis typically involves a porcelain furnace and a muffle oven, in contrast with pyrolytic processes that need a tubular furnace to enable the movement of inert chemicals.

Even though the semi-closed pyrolytic ambient air settings may encourage the burning of carbon to carbon-monoxide or -dioxide, resulting in a drop in electrocatalytic output, it has the benefit of fewer complications and being more economical than those generated on a lab-scale via a tubular furnace.

Important Conclusions

This paper describes a simple technique for synthesizing g-C3N4@rGO oxygen reduction reaction electrocatalyst by semi-closed pyrolysis of graphene oxide and urea. The results of XRD and FTIR analyses indicated that the desired g-C3N4/rGO interlayer composite was successfully formed.

The resultant g-C3N4@rGO had around 12 percent nitrogen, with 61 percent consisting of the desired graphitic and pyridinic N. Given the availability of active areas in g-C3N4 and N-loaded reduced graphene oxide, electrochemical analysis showed that the g-C3N4@rGO produced by semi-closed pyrolysis might catalyze ORR in alkaline conditions.

The electrochemical analysis revealed similar but poorer ORR performance compared to Pt/C. Regarding electrolytic stability, g-C3N4@rGO was shown to be better than Pt/C.

Despite its comparatively inferior performance in ORR electrocatalysis in contrast with other g-C3N4/graphene hybrids, the semi-closed pyrolysis approach was simpler and cheaper than alternative techniques in the literature.

The employment of urea as a g-C3N4 precursor increased this method's benefits by offering a low-cost, sustainable, and safe raw ingredient for producing ORR electrocatalysts. To enhance the advantages of g-C3N4@rGO in ORR electrocatalysis, additional improvement of the semi-closed pyrolysis technique would be required.

Reference

Garcia, J. L., Miyao, T., Inukai, J., & Tongol, B. J. (2022). Graphitic carbon nitride on reduced graphene oxide prepared via semi-closed pyrolysis as electrocatalyst for oxygen reduction reaction. Materials Chemistry and Physics. Available at: https://doi.org/10.1016/j.matchemphys.2022.126415

Disclaimer: The views expressed here are those of the author expressed in their private capacity and do not necessarily represent the views of AZoM.com Limited T/A AZoNetwork the owner and operator of this website. This disclaimer forms part of the Terms and conditions of use of this website.

Shaheer Rehan

Written by

Shaheer Rehan

Shaheer is a graduate of Aerospace Engineering from the Institute of Space Technology, Islamabad. He has carried out research on a wide range of subjects including Aerospace Instruments and Sensors, Computational Dynamics, Aerospace Structures and Materials, Optimization Techniques, Robotics, and Clean Energy. He has been working as a freelance consultant in Aerospace Engineering for the past year. Technical Writing has always been a strong suit of Shaheer's. He has excelled at whatever he has attempted, from winning accolades on the international stage in match competitions to winning local writing competitions. Shaheer loves cars. From following Formula 1 and reading up on automotive journalism to racing in go-karts himself, his life revolves around cars. He is passionate about his sports and makes sure to always spare time for them. Squash, football, cricket, tennis, and racing are the hobbies he loves to spend his time in.

Citations

Please use one of the following formats to cite this article in your essay, paper or report:

  • APA

    Rehan, Shaheer. (2022, June 20). Sustainable Synthesis of Carbon-Based Oxygen Reduction Reaction Electrocatalyst. AZoNano. Retrieved on June 29, 2022 from https://www.azonano.com/news.aspx?newsID=39293.

  • MLA

    Rehan, Shaheer. "Sustainable Synthesis of Carbon-Based Oxygen Reduction Reaction Electrocatalyst". AZoNano. 29 June 2022. <https://www.azonano.com/news.aspx?newsID=39293>.

  • Chicago

    Rehan, Shaheer. "Sustainable Synthesis of Carbon-Based Oxygen Reduction Reaction Electrocatalyst". AZoNano. https://www.azonano.com/news.aspx?newsID=39293. (accessed June 29, 2022).

  • Harvard

    Rehan, Shaheer. 2022. Sustainable Synthesis of Carbon-Based Oxygen Reduction Reaction Electrocatalyst. AZoNano, viewed 29 June 2022, https://www.azonano.com/news.aspx?newsID=39293.

Tell Us What You Think

Do you have a review, update or anything you would like to add to this news story?

Leave your feedback
Your comment type
Submit