Scientists Develop High-Pressure Enabled Atomic Force Microscope to Study Geochemical Processes
It is a challenging task to study the behavior of CO2 with instruments under geological conditions involving high-pressure. A new atomic force microscope (AFM) was developed by scientists at Lawrence Berkeley National Laboratory, Wright State University and Pacific Northwest National Laboratory to withstand the pressure encountered by stored greenhouse gases underground.
Images taken by the atomic force microscope
Scientists can view images and movies of reactions as and when they take place under similar conditions as at a carbon sequestration site using the new AFM. Removing CO2 from industrial emissions and accumulating it underground enables researchers to give answers to some basic questions such as the interaction of carbon dioxide with adjacent mineral surfaces. The new device provides the required answers.
CO2 is injected into porous rocks present underground at a distance of more than half a mile below the surface, where the pressure and temperature conditions are favorable to sustain CO2 in a supercritical fluid state. At this state, CO2 exhibits both liquid and gaseous properties. Researchers wanted to observe a real time viewing of the reactions taking place under native environmental conditions. The chemical interactions between minerals present in rock formations and supercritical CO2 could be understood better with the help of the images.
The researchers designed an apparatus to enable an atomic force microscope to withstand temperatures approximately up to 350°K and pressures of 100 atm. Scientists used this microscope to produce images and a real-time film of the reaction of supercritical CO2 with a hydrated calcite surface. Calcite surfaces are easy to prepare and they can be used for AFM studies. It can also be used to observe other chemical reactions taking place at high pressures.
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