Posted in | News | Nanomaterials | Nanoanalysis

Nanoadditives Influence Alternative Construction Material

In an article published recently in the journal Materials, the coupled influence of graphene oxide (GO) and oxidized multi-walled carbon nanotubes (OMWCNTs) on material characteristics of magnesium oxychloride cement (MOC) phase 5 was investigated.

Nanoadditives Influence Alternative Construction Material

Study: Co-Doped Magnesium Oxychloride Composites with Unique Flexural Strength for Construction Use. Image Credit: Bannafarsai_Stock/Shutterstock.com

An Introduction to Magnesium Oxychloride Cement

Recent breakthroughs in magnesium oxychloride cement (MOC) research indicate a potential future in the domain of alternate building elements.

MOC is often regarded as an ecologically friendly and efficient building material since it is a non-hydraulic adhesive made from lightly burned magnesia.

The material itself has good flexural and compressive strengths, is fireproof, and has a very quick setting time. Because of its capacity to bind a wide variety of additives, it is possible to improve its qualities with different fillers and to build materials with highly specific characteristics that may be used in many fields of the construction sector.

It is feasible to utilize large amounts of supplementary fillers, such as glass powder, diatomite, wood aggregates, fly ash, lunar regolith simulants, and others, to make an environmentally friendly composite while preserving strength and rigidity.

Micrographs of OMWCNTs (left) and GO (right) observed using SEM.

Figure 1. Micrographs of OMWCNTs (left) and GO (right) observed using SEM. © Lauermannová, A.-M., Jankovský, O., et al. (2022).

MOC synthesis is fairly straightforward and based on the molar concentration of the raw ingredients.

MOC phase 5 is the most popular and widely utilized form of this system, which crystallizes as needle-like bristles.

One of the probable explanations for the adhesive's great strength is the interconnecting of these crystalline whiskers. The capacity of MOC to capture carbon dioxide from the environment also influences its characteristics, resulting in the production of magnesium carbonate layers on the exterior of MOC.

The Main Drawback of MOC

MOC's most significant disadvantage is its poor hydrophobicity.

The degradation of MOC in aqueous environments, as well as the reactivity of MOC phases with water to create brucite, have previously been documented.

As a result of this process, the mechanical strength quickly declines, resulting in the leakage of magnesium chloride and the formation of a corrosive medium. As a result, such materials cannot be used in conjunction with steel supports; alternate reinforcements must be investigated.

A viable answer to this challenge may be found in the field of carbonaceous nanomaterials.

Functionalization of Carbon Nanoadditives

The typical employment of carbonaceous nanoparticles in building composites depends on the incorporation of a moderate quantity of the nanomaterial into the substrate while gaining a significant improvement in material characteristics.

This stems from the exceptional characteristics of carbonaceous nanoparticles, which include great compressive strength, good thermal and electrical conductance, and excellent optical qualities.

Graphene and its variants are examples of two-dimensional carbon nanomaterials. Fluorine, sulfur, boron, nitrogen, and other elements may be used to modify graphene.

The 1D category of carbon nanomaterials includes multi-walled carbon nanotubes (MWCNTs) and their derivatives. MWCNTs, like graphene, may be changed to produce a wide range of derivatives with diverse functional groups.

28-days specimens: MOC-REF, MOC-GO-OMWCNT-0.1, MOC-GO-OMWCNT-0.2 (from left).

Figure 2. 28-days specimens: MOC-REF, MOC-GO-OMWCNT-0.1, MOC-GO-OMWCNT-0.2 (from left) © Lauermannová, A.-M., Jankovský, O., et al. (2022).

Due to their water-repellant nature, carbon nanotubes and graphene have a poor water distribution, limiting their application in regular building composites.

Because the hydrophobicity of these substances may be changed by functionalization, their distribution in the composite matrix is considerably simpler. The interaction of these nanoscale additives with powerful acids results in the creation of their oxidized counterparts, which may influence the mechanical characteristics of the overall composite.

Important Findings of the Study

The combined impact of oxidized one-dimensional and two-dimensional carbonaceous nanoadditives on MOC Phase 5 was investigated in this study.

The carbonaceous nanoadditives greatly reduced pores, resulting in an improvement in mechanical characteristics, where the flexural strength rose.

The water transportation and storing qualities of the MOC matrix were substantially reduced with the decrease in volume of pores as a result of their filling and interconnecting with the nanoscale additives; thus, the enhanced hydrophobicity of the MOC framework can be predicted – this effect of the nanodopants is critical for the MOC-based composites.

The heat conduction of the composite was fairly high, owing to the reduced porosity, but also to the adaptation of the heat conductivity of the utilized GO and OMWCNTs, which is usually pretty high.

The XRD patterns of the samples MOC-REF (top), MOC-GO-OMWCNT-0.1 (middle) and MOC-GO-OMWCNT-0.2 (bottom).

Figure 3. The XRD patterns of the samples MOC-REF (top), MOC-GO-OMWCNT-0.1 (middle) and MOC-GO-OMWCNT-0.2 (bottom) © Lauermannová, A.-M., Jankovský, O., et al. (2022).

On the basis of these findings, it was determined that the nanoadditives utilized had substantial promise in the formulation and production of sophisticated and versatile MOC-based composites. However, to achieve even larger augmentation of the composite characteristics, the homogeneity and optimal distribution of the nanodopants must be enhanced.

Continue reading: How Can Concrete Properties be Controlled with Nanotechnology?

Reference

Lauermannová, A.-M., Jankovský, O., et al. (2022). Co-Doped Magnesium Oxychloride Composites with Unique Flexural Strength for Construction Use. Materials, 15(2). Available at: https://www.mdpi.com/1996-1944/15/2/604

Disclaimer: The views expressed here are those of the author expressed in their private capacity and do not necessarily represent the views of AZoM.com Limited T/A AZoNetwork the owner and operator of this website. This disclaimer forms part of the Terms and conditions of use of this website.

Shaheer Rehan

Written by

Shaheer Rehan

Shaheer is a graduate of Aerospace Engineering from the Institute of Space Technology, Islamabad. He has carried out research on a wide range of subjects including Aerospace Instruments and Sensors, Computational Dynamics, Aerospace Structures and Materials, Optimization Techniques, Robotics, and Clean Energy. He has been working as a freelance consultant in Aerospace Engineering for the past year. Technical Writing has always been a strong suit of Shaheer's. He has excelled at whatever he has attempted, from winning accolades on the international stage in match competitions to winning local writing competitions. Shaheer loves cars. From following Formula 1 and reading up on automotive journalism to racing in go-karts himself, his life revolves around cars. He is passionate about his sports and makes sure to always spare time for them. Squash, football, cricket, tennis, and racing are the hobbies he loves to spend his time in.

Citations

Please use one of the following formats to cite this article in your essay, paper or report:

  • APA

    Rehan, Shaheer. (2022, January 18). Nanoadditives Influence Alternative Construction Material. AZoNano. Retrieved on June 25, 2022 from https://www.azonano.com/news.aspx?newsID=38531.

  • MLA

    Rehan, Shaheer. "Nanoadditives Influence Alternative Construction Material". AZoNano. 25 June 2022. <https://www.azonano.com/news.aspx?newsID=38531>.

  • Chicago

    Rehan, Shaheer. "Nanoadditives Influence Alternative Construction Material". AZoNano. https://www.azonano.com/news.aspx?newsID=38531. (accessed June 25, 2022).

  • Harvard

    Rehan, Shaheer. 2022. Nanoadditives Influence Alternative Construction Material. AZoNano, viewed 25 June 2022, https://www.azonano.com/news.aspx?newsID=38531.

Tell Us What You Think

Do you have a review, update or anything you would like to add to this news story?

Leave your feedback
Your comment type
Submit