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Eco-Friendly Filtration of Microplastics Using Iron Oxide Nanoparticles

Filtering out microplastics from water is difficult because they can bypass most filtration systems owing to their microscopic size. In a study published in the journal Chemosphere, magnetic iron oxide (Fe3O4) nanoparticles were evaluated as potential candidates for the adsorptive removal of microplastics.

Eco-Friendly Filtration of Microplastics Using Iron Oxide Nanoparticles

Study: Adsorptive removal of micron-sized polystyrene particles using magnetic iron oxide nanoparticles. Image Credit: chayanuphol/Shutterstock.com

Harmful Effects of Plastic Pollution

Increased plastic demand has to an increase in plastic pollution, which can have significant consequences for natural ecosystems as well as human health and safety. Inadequate recycling and mishandling of plastic worsen plastic pollution.

Plastics have extended breakdown durations and are likely to accumulate in the ecosystem because of their high stability and durability. Growing plastic levels in the environment, particularly in marine ecosystems, lead to growing concern for the environment. Plastic is carried to water bodies by wind and ocean currents, and it fragments into micro and nanoplastics over time.

It is difficult for living organisms to avoid consuming plastic waste because of the universal nature of microplastics. Once consumed, these microplastics are transferred up the food chain and may ultimately have a negative impact on human health.

How Can Microplastics be Removed from Water?

To remove microplastics from wastewater and drinking water magnetic extraction, electrocoagulation, and membrane separation technologies are suggested. However, it is difficult to eliminate microplastics having diameters smaller than 1 μm. So, these microplastics are common in wastewater treatment facilities.

To successfully eliminate microplastics from water, a consistent, simple, quick, and repeatable technique must be developed.

Removing Pollutants with Iron Oxide Nanoparticles

As nanoparticles tend to have high specific areas, a cluster of iron oxide (Fe3O4) nanoparticles has a relatively high adsorption site density. Therefore, iron oxide nanoparticles have been employed in a variety of areas, including the removal of contaminants in the environment.

The magnetic effects of iron oxide enable quicker removal of contaminant nanoparticles in comparison with centrifuge machines and filtering procedures.

Once magnetic separation and regenerative processes are finished, the iron oxide nanoparticles may be reused, making them a viable adsorption material for eliminating environmental contaminants.

What Did the Researchers Do?

The team investigated the use of magnetic Fe3O4 nanoparticles for filtering out microplastics from water via adsorption. To model the behavior of microplastics, polystyrene (PS) microparticles were used.

The researchers examined the process kinetics and isothermal adsorptive characteristics of polystyrene microparticles on Fe3O4 nanoparticles.

They also conducted adsorptive tests for different groups of polystyrene microparticles with various average diameters to look into the adsorbing effectiveness of Fe3O4 nanoparticles. The hydrophobic and electrostatic dynamics involved in the adsorption process of Fe3O4 and polystyrene microparticles were investigated as well.

The team also determined the reusability of Fe3O4 nanoparticles by desorbing them from Fe3O4-polystyrene complexes (Fe3O4-PS).

Main Findings of the Research

In this study, the team managed to successfully extract polystyrene microparticles from liquid environments using the combined effect of Fe3O4 nanoparticles and a magnet. The attachment of the polystyrene microparticles onto the Fe3O4 nanoparticles enabled this process.

It was observed in TEM imaging that the Fe3O4 nanoparticles encompassed and gathered the polystyrene microparticles, enabling a magnet to be used for extracting the resultant Fe3O4-polystyrene complexes from the fluid.

It was established that the agglomeration of Fe3O4 with polystyrene microparticles was mostly due to hydrophobic interaction among them. When an actual sample of water was analyzed, suspended solid matter and coinciding ions present in the sample impeded the deposition of polystyrene microparticles onto Fe3O4 nanoparticles. Nonetheless, adsorption effectiveness may be enhanced by incorporating larger quantities of the adsorbent Fe3O4 nanoparticles.

Fe3O4 nanoparticles were separated from the Fe3O4-polystyrene complexes using a straightforward sonication procedure. The research highlighted the potential of employing Fe3O4 nanoparticles to efficiently eliminate microplastics from the ecosystem.

References

Heo, Y., Lee, E.-H., & Lee, S.-W. (2022). Adsorptive removal of micron-sized polystyrene particles using magnetic iron oxide nanoparticles. Chemosphere. Available at: https://doi.org/10.1016/j.chemosphere.2022.135672

Disclaimer: The views expressed here are those of the author expressed in their private capacity and do not necessarily represent the views of AZoM.com Limited T/A AZoNetwork the owner and operator of this website. This disclaimer forms part of the Terms and conditions of use of this website.

Shaheer Rehan

Written by

Shaheer Rehan

Shaheer is a graduate of Aerospace Engineering from the Institute of Space Technology, Islamabad. He has carried out research on a wide range of subjects including Aerospace Instruments and Sensors, Computational Dynamics, Aerospace Structures and Materials, Optimization Techniques, Robotics, and Clean Energy. He has been working as a freelance consultant in Aerospace Engineering for the past year. Technical Writing has always been a strong suit of Shaheer's. He has excelled at whatever he has attempted, from winning accolades on the international stage in match competitions to winning local writing competitions. Shaheer loves cars. From following Formula 1 and reading up on automotive journalism to racing in go-karts himself, his life revolves around cars. He is passionate about his sports and makes sure to always spare time for them. Squash, football, cricket, tennis, and racing are the hobbies he loves to spend his time in.

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